Birinci Mertebeden Reaksiyonlarda Konsantrasyon Değişimi

SORU

Radyoktif bir maddenin zamanla konsantrasyon değişimi

[A]=[A]oe-kt 
eşitliği ile izlenir.

Burada [A]o; A maddesinin başlangıç konsantrasyonu, [A]; maddenin t süresi konundaki konsantrasyonu ve k; maddenin bozunma hız sabitidir.

Böyle bir maddenin yarılanma süresi, t1/2, ([A]o ın [A]o/2 ye düşme zamanı) ile k arasında ise

k = ln(2)/t1/2 

ilişkisi bulunur.

14C izotopunun yarılanma süresi 5730 yıldır. Buna göre 5.000 gram 0.500 grama düşünceye her 10 yılda bir hesaplama yapan bir betik hazırlayınız.

Not :
YANIT

Algoritma :

  1. Program ilk çağrıldığında [A]o, [A] ve t1/2 değişken değerleri boş olduğundan bu değişkenlere otomatik olarak değişken değeri atanmalıdır.
  2. k=ln(2)/t1/2 eşitliğinden k yı hesapla
  3. Zamanı 10 ar yıl arrtır ve her arttırmada [A]=[A]oe-kt eşitliğinden [A] değerini hesapla.
  4. [A] değeri ineceği minimum değere inmediğinde Zaman - [A] bilgisini göster
  5. [A] ineceği minimum değere indiğinde veya 0 veya 0 dan küçükse döndüğü sonlandır.

PROGRAM KODU
<?php
$t12=$_POST[t12];
$Ao=$_POST[Ao];
$Ason=$_POST[Ason];
if (empty($t12)) {$t12=5730;}
if (empty($Ao)) {$Ao=5.000;}
if (empty($Ason)) {$Ason=0.500;}
$DS=$_POST[DS];

echo "<form name='PV' action=$_SERVER[PHP_SELF] method='post'>
<fieldset><legend>Veriler</legend>
<table align='left'>
<tr>
<td>A maddesinin yarılanma Zamanı</td>
<td>:</td>
<td><input type='text' name='t12' value='$t12' size='4' maxlength='5' /> yıl</td>
</tr>

<tr>
<td>A maddesinin ilk miktarı</td>
<td>:</td>
<td><input type='text' name='Ao' value='".sprintf("%2.3f",$Ao)."' size='3' maxlength='4' /> g.</td>
</tr>

<tr>
<td>A maddesinin son miktarı</td>
<td>:</td>
<td><input type='text' name='Ason' value='".sprintf("%2.3f",$Ason)."' size='3' maxlength='4' /> g.</td>
</tr>

<tr>
<td colspan='3' align='right'><input type='submit' name='Hesapla' ></td>
</tr>

</table>
</fieldset>
";

$k=log(2)/$t12;
echo "<fieldset><legend>Sonuçlar</legend><table border='1'><tr><th>Yıl</th><th>[A]</th></tr>";
for($Zaman=0;;$Zaman=$Zaman+10)
{
$A=sprintf("%2.4f",$Ao*exp(-$k*$Zaman));
if($A>$Ason){echo "<tr><td>$Zaman</th><th>$A</td></tr>";}

if ($A<=$Ason || $A<=0) { echo "<tr><td>$Zaman</th><th>---</td></tr></table><fieldset>";break;}
}

?>

ÇALIŞAN PROGRAM
Veriler
A maddesinin yarılanma Zamanı : yıl
A maddesinin ilk miktarı : g.
A maddesinin son miktarı : g.
Sonuçlar
Yıl[A]
05.0000
104.9940
204.9879
304.9819
404.9759
504.9698
604.9638
704.9578
804.9518
904.9459
1004.9399
1104.9339
1204.9279
1304.9220
1404.9160
1504.9101
1604.9042
1704.8982
1804.8923
1904.8864
2004.8805
2104.8746
2204.8687
2304.8628
2404.8569
2504.8511
2604.8452
2704.8393
2804.8335
2904.8276
3004.8218
3104.8160
3204.8101
3304.8043
3404.7985
3504.7927
3604.7869
3704.7811
3804.7754
3904.7696
4004.7638
4104.7581
4204.7523
4304.7466
4404.7408
4504.7351
4604.7294
4704.7237
4804.7179
4904.7122
5004.7065
5104.7009
5204.6952
5304.6895
5404.6838
5504.6782
5604.6725
5704.6669
5804.6612
5904.6556
6004.6500
6104.6443
6204.6387
6304.6331
6404.6275
6504.6219
6604.6163
6704.6107
6804.6052
6904.5996
7004.5940
7104.5885
7204.5829
7304.5774
7404.5719
7504.5663
7604.5608
7704.5553
7804.5498
7904.5443
8004.5388
8104.5333
8204.5278
8304.5224
8404.5169
8504.5114
8604.5060
8704.5005
8804.4951
8904.4897
9004.4842
9104.4788
9204.4734
9304.4680
9404.4626
9504.4572
9604.4518
9704.4464
9804.4410
9904.4357
10004.4303
10104.4250
10204.4196
10304.4143
10404.4089
10504.4036
10604.3983
10704.3930
10804.3876
10904.3823
11004.3770
11104.3717
11204.3665
11304.3612
11404.3559
11504.3506
11604.3454
11704.3401
11804.3349
11904.3296
12004.3244
12104.3192
12204.3140
12304.3087
12404.3035
12504.2983
12604.2931
12704.2879
12804.2828
12904.2776
13004.2724
13104.2673
13204.2621
13304.2569
13404.2518
13504.2467
13604.2415
13704.2364
13804.2313
13904.2262
14004.2210
14104.2159
14204.2108
14304.2058
14404.2007
14504.1956
14604.1905
14704.1855
14804.1804
14904.1753
15004.1703
15104.1652
15204.1602
15304.1552
15404.1502
15504.1451
15604.1401
15704.1351
15804.1301
15904.1251
16004.1201
16104.1152
16204.1102
16304.1052
16404.1003
16504.0953
16604.0904
16704.0854
16804.0805
16904.0755
17004.0706
17104.0657
17204.0608
17304.0559
17404.0510
17504.0461
17604.0412
17704.0363
17804.0314
17904.0265
18004.0217
18104.0168
18204.0119
18304.0071
18404.0022
18503.9974
18603.9926
18703.9878
18803.9829
18903.9781
19003.9733
19103.9685
19203.9637
19303.9589
19403.9541
19503.9493
19603.9446
19703.9398
19803.9350
19903.9303
20003.9255
20103.9208
20203.9160
20303.9113
20403.9066
20503.9019
20603.8971
20703.8924
20803.8877
20903.8830
21003.8783
21103.8736
21203.8690
21303.8643
21403.8596
21503.8549
21603.8503
21703.8456
21803.8410
21903.8363
22003.8317
22103.8271
22203.8224
22303.8178
22403.8132
22503.8086
22603.8040
22703.7994
22803.7948
22903.7902
23003.7856
23103.7810
23203.7765
23303.7719
23403.7674
23503.7628
23603.7582
23703.7537
23803.7492
23903.7446
24003.7401
24103.7356
24203.7311
24303.7266
24403.7221
24503.7176
24603.7131
24703.7086
24803.7041
24903.6996
25003.6951
25103.6907
25203.6862
25303.6818
25403.6773
25503.6729
25603.6684
25703.6640
25803.6596
25903.6551
26003.6507
26103.6463
26203.6419
26303.6375
26403.6331
26503.6287
26603.6243
26703.6199
26803.6155
26903.6112
27003.6068
27103.6025
27203.5981
27303.5937
27403.5894
27503.5851
27603.5807
27703.5764
27803.5721
27903.5678
28003.5634
28103.5591
28203.5548
28303.5505
28403.5462
28503.5420
28603.5377
28703.5334
28803.5291
28903.5249
29003.5206
29103.5163
29203.5121
29303.5078
29403.5036
29503.4994
29603.4951
29703.4909
29803.4867
29903.4825
30003.4783
30103.4741
30203.4699
30303.4657
30403.4615
30503.4573
30603.4531
30703.4489
30803.4448
30903.4406
31003.4364
31103.4323
31203.4281
31303.4240
31403.4199
31503.4157
31603.4116
31703.4075
31803.4033
31903.3992
32003.3951
32103.3910
32203.3869
32303.3828
32403.3787
32503.3746
32603.3706
32703.3665
32803.3624
32903.3584
33003.3543
33103.3502
33203.3462
33303.3421
33403.3381
33503.3341
33603.3300
33703.3260
33803.3220
33903.3180
34003.3140
34103.3100
34203.3060
34303.3020
34403.2980
34503.2940
34603.2900
34703.2860
34803.2821
34903.2781
35003.2741
35103.2702
35203.2662
35303.2623
35403.2583
35503.2544
35603.2504
35703.2465
35803.2426
35903.2387
36003.2348
36103.2308
36203.2269
36303.2230
36403.2191
36503.2152
36603.2114
36703.2075
36803.2036
36903.1997
37003.1959
37103.1920
37203.1881
37303.1843
37403.1804
37503.1766
37603.1727
37703.1689
37803.1651
37903.1613
38003.1574
38103.1536
38203.1498
38303.1460
38403.1422
38503.1384
38603.1346
38703.1308
38803.1270
38903.1232
39003.1195
39103.1157
39203.1119
39303.1082
39403.1044
39503.1007
39603.0969
39703.0932
39803.0894
39903.0857
40003.0820
40103.0782
40203.0745
40303.0708
40403.0671
40503.0634
40603.0597
40703.0560
40803.0523
40903.0486
41003.0449
41103.0412
41203.0375
41303.0339
41403.0302
41503.0265
41603.0229
41703.0192
41803.0156
41903.0119
42003.0083
42103.0047
42203.0010
42302.9974
42402.9938
42502.9901
42602.9865
42702.9829
42802.9793
42902.9757
43002.9721
43102.9685
43202.9649
43302.9614
43402.9578
43502.9542
43602.9506
43702.9471
43802.9435
43902.9399
44002.9364
44102.9328
44202.9293
44302.9257
44402.9222
44502.9187
44602.9151
44702.9116
44802.9081
44902.9046
45002.9011
45102.8976
45202.8941
45302.8906
45402.8871
45502.8836
45602.8801
45702.8766
45802.8731
45902.8697
46002.8662
46102.8627
46202.8593
46302.8558
46402.8524
46502.8489
46602.8455
46702.8420
46802.8386
46902.8352
47002.8317
47102.8283
47202.8249
47302.8215
47402.8181
47502.8147
47602.8113
47702.8079
47802.8045
47902.8011
48002.7977
48102.7943
48202.7909
48302.7875
48402.7842
48502.7808
48602.7774
48702.7741
48802.7707
48902.7674
49002.7640
49102.7607
49202.7574
49302.7540
49402.7507
49502.7474
49602.7441
49702.7407
49802.7374
49902.7341
50002.7308
50102.7275
50202.7242
50302.7209
50402.7176
50502.7143
50602.7111
50702.7078
50802.7045
50902.7012
51002.6980
51102.6947
51202.6915
51302.6882
51402.6849
51502.6817
51602.6785
51702.6752
51802.6720
51902.6688
52002.6655
52102.6623
52202.6591
52302.6559
52402.6527
52502.6495
52602.6463
52702.6431
52802.6399
52902.6367
53002.6335
53102.6303
53202.6271
53302.6239
53402.6208
53502.6176
53602.6144
53702.6113
53802.6081
53902.6050
54002.6018
54102.5987
54202.5955
54302.5924
54402.5893
54502.5861
54602.5830
54702.5799
54802.5768
54902.5736
55002.5705
55102.5674
55202.5643
55302.5612
55402.5581
55502.5550
55602.5519
55702.5489
55802.5458
55902.5427
56002.5396
56102.5366
56202.5335
56302.5304
56402.5274
56502.5243
56602.5213
56702.5182
56802.5152
56902.5121
57002.5091
57102.5061
57202.5030
57302.5000
57402.4970
57502.4940
57602.4909
57702.4879
57802.4849
57902.4819
58002.4789
58102.4759
58202.4729
58302.4699
58402.4670
58502.4640
58602.4610
58702.4580
58802.4550
58902.4521
59002.4491
59102.4462
59202.4432
59302.4402
59402.4373
59502.4343
59602.4314
59702.4285
59802.4255
59902.4226
60002.4197
60102.4167
60202.4138
60302.4109
60402.4080
60502.4051
60602.4022
60702.3993
60802.3964
60902.3935
61002.3906
61102.3877
61202.3848
61302.3819
61402.3790
61502.3762
61602.3733
61702.3704
61802.3675
61902.3647
62002.3618
62102.3590
62202.3561
62302.3533
62402.3504
62502.3476
62602.3447
62702.3419
62802.3391
62902.3363
63002.3334
63102.3306
63202.3278
63302.3250
63402.3222
63502.3194
63602.3166
63702.3138
63802.3110
63902.3082
64002.3054
64102.3026
64202.2998
64302.2970
64402.2942
64502.2915
64602.2887
64702.2859
64802.2832
64902.2804
65002.2777
65102.2749
65202.2721
65302.2694
65402.2667
65502.2639
65602.2612
65702.2584
65802.2557
65902.2530
66002.2503
66102.2475
66202.2448
66302.2421
66402.2394
66502.2367
66602.2340
66702.2313
66802.2286
66902.2259
67002.2232
67102.2205
67202.2178
67302.2152
67402.2125
67502.2098
67602.2071
67702.2045
67802.2018
67902.1991
68002.1965
68102.1938
68202.1912
68302.1885
68402.1859
68502.1832
68602.1806
68702.1780
68802.1753
68902.1727
69002.1701
69102.1674
69202.1648
69302.1622
69402.1596
69502.1570
69602.1544
69702.1518
69802.1492
69902.1466
70002.1440
70102.1414
70202.1388
70302.1362
70402.1336
70502.1310
70602.1285
70702.1259
70802.1233
70902.1208
71002.1182
71102.1156
71202.1131
71302.1105
71402.1080
71502.1054
71602.1029
71702.1003
71802.0978
71902.0953
72002.0927
72102.0902
72202.0877
72302.0851
72402.0826
72502.0801
72602.0776
72702.0751
72802.0726
72902.0701
73002.0676
73102.0651
73202.0626
73302.0601
73402.0576
73502.0551
73602.0526
73702.0501
73802.0477
73902.0452
74002.0427
74102.0402
74202.0378
74302.0353
74402.0328
74502.0304
74602.0279
74702.0255
74802.0230
74902.0206
75002.0181
75102.0157
75202.0133
75302.0108
75402.0084
75502.0060
75602.0035
75702.0011
75801.9987
75901.9963
76001.9939
76101.9915
76201.9891
76301.9867
76401.9843
76501.9819
76601.9795
76701.9771
76801.9747
76901.9723
77001.9699
77101.9675
77201.9651
77301.9628
77401.9604
77501.9580
77601.9557
77701.9533
77801.9509
77901.9486
78001.9462
78101.9439
78201.9415
78301.9392
78401.9368
78501.9345
78601.9321
78701.9298
78801.9275
78901.9251
79001.9228
79101.9205
79201.9182
79301.9158
79401.9135
79501.9112
79601.9089
79701.9066
79801.9043
79901.9020
80001.8997
80101.8974
80201.8951
80301.8928
80401.8905
80501.8882
80601.8860
80701.8837
80801.8814
80901.8791
81001.8769
81101.8746
81201.8723
81301.8701
81401.8678
81501.8655
81601.8633
81701.8610
81801.8588
81901.8565
82001.8543
82101.8520
82201.8498
82301.8476
82401.8453
82501.8431
82601.8409
82701.8387
82801.8364
82901.8342
83001.8320
83101.8298
83201.8276
83301.8254
83401.8231
83501.8209
83601.8187
83701.8165
83801.8143
83901.8122
84001.8100
84101.8078
84201.8056
84301.8034
84401.8012
84501.7990
84601.7969
84701.7947
84801.7925
84901.7904
85001.7882
85101.7860
85201.7839
85301.7817
85401.7796
85501.7774
85601.7753
85701.7731
85801.7710
85901.7688
86001.7667
86101.7646
86201.7624
86301.7603
86401.7582
86501.7560
86601.7539
86701.7518
86801.7497
86901.7476
87001.7455
87101.7433
87201.7412
87301.7391
87401.7370
87501.7349
87601.7328
87701.7307
87801.7286
87901.7266
88001.7245
88101.7224
88201.7203
88301.7182
88401.7161
88501.7141
88601.7120
88701.7099
88801.7079
88901.7058
89001.7037
89101.7017
89201.6996
89301.6976
89401.6955
89501.6935
89601.6914
89701.6894
89801.6873
89901.6853
90001.6832
90101.6812
90201.6792
90301.6772
90401.6751
90501.6731
90601.6711
90701.6691
90801.6670
90901.6650
91001.6630
91101.6610
91201.6590
91301.6570
91401.6550
91501.6530
91601.6510
91701.6490
91801.6470
91901.6450
92001.6430
92101.6410
92201.6390
92301.6371
92401.6351
92501.6331
92601.6311
92701.6292
92801.6272
92901.6252
93001.6233
93101.6213
93201.6193
93301.6174
93401.6154
93501.6135
93601.6115
93701.6096
93801.6076
93901.6057
94001.6037
94101.6018
94201.5999
94301.5979
94401.5960
94501.5941
94601.5921
94701.5902
94801.5883
94901.5864
95001.5845
95101.5825
95201.5806
95301.5787
95401.5768
95501.5749
95601.5730
95701.5711
95801.5692
95901.5673
96001.5654
96101.5635
96201.5616
96301.5597
96401.5578
96501.5560
96601.5541
96701.5522
96801.5503
96901.5485
97001.5466
97101.5447
97201.5428
97301.5410
97401.5391
97501.5373
97601.5354
97701.5335
97801.5317
97901.5298
98001.5280
98101.5261
98201.5243
98301.5225
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